First, the batching calculation according to the following conditions
(1) To refining carbon manganese iron component is: w (Mn)> 78%
, w (C) from about 1.25%, w (P) < 0.25%, w (Si) 1.5%.
(2) The raw material components are shown in Table 1.

Table 1   Raw material composition (%)

name

Mn

P

C

Si

Fe

CaO

MgO

SiO 2

Mixed manganese ore

40

0.09

1.25

19

5.3

0.5

0.4

14

Manganese silicon alloy

67

0.16

 

 

lime

 

 

85

0.7

(3) The distribution of each element in manganese ore is shown in Table 2.

Table 2   Element allocation (%)

element

Into the alloy

Slag

Volatilization

Mn

30

50

20

Fe

90

10

 

P

70

5

25

(4) The elements in the manganese-silicon alloy are distributed as follows: 8% silicon into the alloy, silicon utilization rate is 75% (excluding 8% entering the alloy), and manganese, iron and phosphorus are 100% into the alloy.
(5) slag basicity n (CaO) / n (SiO 2 ) = 1.4.
(6) Based on the calculation of 100kg manganese ore, the amount of manganese-silicon alloy and the amount of lime are required.
Second, the ingredients calculation
(1) Calculation of the amount of manganese-silicon alloy The calculation of the amount of silicon required is shown in Table 3.
The amount of manganese silicon alloy is

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(2) Calculation of lime dosage The amount of SiO 2 introduced by manganese ore is 100×0.14=14 (kg)
The amount of SiO 2 formed by silicon in the manganese-silicon alloy is

The batch composition is: manganese ore 100kg; manganese silicon alloy 72.56kg; lime 68kg.
(3) Calculation of alloy quality and composition The sum of the elements of manganese silicon alloy entering the product is 72.56-72.56×0.19×0.92=59.87(kg)
The amount of manganese in the manganese ore is 100×0.4×0.3=12 (kg)
The amount of phosphorus in the manganese ore is 100×0.0009×0.7=0.06(kg)
The total amount of alloy is 59.87+12+4.77+0.06=76.70(kg)
Alloy composition is

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(4) Calculation of the amount of slag and its composition The number and composition of slag are shown in Table 4.

Table 4   Slag quantity and composition

ingredient

From manganese ore (kg)

From manganese silicon alloy (kg)

From lime (kg)

Total (kg)

Slag composition content /%

MnO

10 0×0.4×0.5×71/55=25.82

 

 

25.82

19.477

SiO 2

100×0.14=14

27.174

6 8×0.007=0.476

41.65

31.419

CaO

100×0.005=0.5

 

6 8×0.85=57.8

58.3

43.98

MgO

100×0.004=0.4

 

 

0.4

0.301

Al 2 O 3

100×0.57=5.7

 

 

5.7

4.299

FeO

100×0.053×0.1×72/56=0.68

 

 

0.68

0.512

P 2 O 5

100×0.0009×0.05×1.42/62=0.01

 

 

0.01

0.0057

total

47.11

27.174

58276

132.56

100

From the above calculation results, the ratio of slag amount to alloy yield can be obtained:

The amount of manganese recovered is calculated as follows:
The manganese in the furnace is: 100×0.4+72.56×0.67=88.6152
Alloy manganese is: 72.56×0.67+12=60.6152
The recovery rate of manganese is: 60.6152/88.615=68.4%

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